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Power

World's First Zinc-Ion Battery Megafactory Opens For Business 67

Sweden's Enerpoly has opened the world's first zinc-ion battery megafactory near Stockholm, aiming for a 100 MWh annual capacity by 2026. "According to Enerpoly, this megafactory will serve Europe's needs for safe energy storage, and also utilize an all-European supply chain to boot," reports New Atlas. From the report: If you're wondering why Enerpoly is bothering with zinc-ion and not lithium-ion batteries, it's because the former is a better choice for storage in several ways:

- They use a water-based electrolyte, which makes them non-flammable, and reduces the risk of fires and explosions.
- They're less expensive, because zinc is far more abundant than lithium (which is difficult and expensive to extract), and easier to handle. They can also operate across a wider temperature range and require less maintenance, making them cheaper than lithium-ion options.
- They're more eco-friendly for the same reason. In contrast, extracting lithium currently requires extensive mining as well as the use of massive evaporation ponds before processing even begins.
- They're said to last a whole lot longer. According to the International Zinc Association, a nonprofit trade association which counts Enerpoly as a member, zinc-based batteries can last up to 20 years, while lithium batteries manage about 12 years.
The downside? They have a lower energy density than something like a Tesla 4680 battery, making them ideal for applications like load shifting and grid resilience.
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World's First Zinc-Ion Battery Megafactory Opens For Business

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  • by Eunomion ( 8640039 ) on Wednesday September 04, 2024 @02:22AM (#64760696)
    One of the most nail-in-coffin criticisms of fossil fuels is that there's just nowhere to go with their evolution anymore without crippling complexity. But batteries still have a huge expanse of possibilities to explore, and small changes that can offer significant trades. A lot of the basic science is already there, but most options have never been tried on an industrial scale. Such diversity will also make it harder to corner and monopolize for more than a short time.
    • by shilly ( 142940 )

      I agree, but I think your comment is also true for the superset of "energy story systems" and not just batteries (ie chemical energy storage systems). Obviously some types of non-battery energy storage have been around for a long time at industrial scale, eg pumped hydro, but there's plenty of promising new types too such as compressed air energy storage, and even for older tech such as pumped hydro, we've never really fully exploited it, because the value of doing so was not so high historically. With the

      • Historically, pumped storage was used to even out the mega Watt fluctuations that happen every second.
        Mostly with the result that the storage needed refilling at night, and the base load plant - which produced to much at that time, where used for that.

        Now we need/want to store massive amounts of excess energy produced by solar and wind. We simply need more plants. And the idea that there is "no suitable place for that" is nonsense. At least in Germany, Portugal, Spain.

        • Historically, pumped storage was used to even out the mega Watt fluctuations that happen every second.
          Mostly with the result that the storage needed refilling at night, and the base load plant - which produced to much at that time, where used for that.

          We've been doing this for our water supply for a long time, hence towers on hills

      • Agreed, the broad diversity of approaches that will now find renewed attention is very exciting. We may well see a Cambrian explosion in energy options, although naturally there will be periodic die-offs and bubble bursts too. Relying so heavily on oil, coal, and natural gas for so long would have been bad for us even if the environmental costs were less extreme.
  • 1. Water-based electrolyte. What else is in the water? I mean, a flooded lead-acid battery also uses a water-based electrolyte, it's just got sulphuric acid added.

    2. A battery is a store of energy. It doesn't go away by itself if something fails. What's the failure mode?

    • Re:Some questions (Score:4, Insightful)

      by Viol8 ( 599362 ) on Wednesday September 04, 2024 @03:59AM (#64760826) Homepage

      "2. A battery is a store of energy. It doesn't go away by itself if something fails. What's the failure mode?"

      I imagine the water would douse any flames and absorb the heat. Lead acids don't burst into flames after trauma, at worst they bubble and boil.

      • For lead-acids, that depends very much on what the acid comes into contact with afterwards! If it lands in quantity on aluminium, for instance, the reaction releases large amounts of hydrogen and heat which can very much lead to combustion.

    • All I can find is that they use a zinc anode, a manganese cathode and a "water-based electrolyte." I'm guessing that means it's proprietary and they aren't saying. Typically such battery chemistries use a complex zinc salt, though there are groups trying zinc sulfate and potassium hydroxide. Notably, all the press releases say a lot about how safe zinc and manganese are and not a lot about the safety of the electrolyte; whether it's dumbing down or whether it's careful wording, I'm not sure.

      For your seco

    • Re:Some questions (Score:5, Interesting)

      by Rei ( 128717 ) on Wednesday September 04, 2024 @07:07AM (#64761064) Homepage

      There's so much more wrong with this hype piece than that.

      * 100 MWh might be a good-sized battery factory in the mid 2010s. It's quite small now. I know, "start somewhere", but if they're going to try to make it sound big, put it into context.

      * You can make li-ion nonflammable as well at the cost of a bit of energy density (and thus cost per kWh). Generally it's just a better idea to manage and contain risk.

      * Batteries are not raw materials costs per kg; there's also large capital costs in manufacturing.And since these cells are just over a third the energy density, you ~3x the cell throughput in your factory and ~3x the raw materials.

      * -10C to 50C is not some sort of impressive temperature range.

      * I have no clue what they mean by "can operate with less maintenance". Exactly what "maintenance" do you think you have to do with li-ion cells?

      * Lithium production does not require "extensive mining as well as the use of massive evaporation ponds", stop this nonsense. You EITHER mine - and it's nt even remotely extensive, as li-ion cells are only 2-3% lithium, and ore at Greenbushes (the largest mine) is up to 50% spodumene (lithium rock). OR you have "massive evaporation ponds", but then there's zero mining, and all you're doing is evaporating non-potable non-fossil (regularly replenished) saltwater, on the middle of a barren salt flat (and producing lots of other salts that are widely used as the same time),

      * Mean time to failure for a Tesla Megapack is 15 years, so "can last up to 20 years" is hardly some super boast, especially for a new product with unknown real-world performance.

      * The cathodes of grid batteries are *also* iron-based (iron phosphate), while the anodes are carbon. Again, lithium is just a couple percent of the cell, and it's not some super-exotic material.

      Every time someone wants to have a go at a different chemistry they push the same sort of nonsense about li-ion batteries. Li-ion batteries gained their crown not because they're terrible, but because they're good really good compared to other rechargeable chemistries. And not just in portable applications. Something surely will unseat it eventually, but it's not going to be a pushover. And what unseats it might *still* be lithium-based (lithium-sulfur, lithium-air, etc) (though my hopes are we'll get a good reversible alumium chemistry, as alumium is light, common, cheap and energetic... the reversibility is not easy, though)

      • Re:Some questions (Score:4, Informative)

        by piojo ( 995934 ) on Wednesday September 04, 2024 @07:27AM (#64761090)

        You missed one :)

        The company says its batteries are suited for 2-10 hour durations, discharging energy over moderate periods.

        In other words the maximum steady discharge rate is 0.5C, compared to li-ion discharge rates in the neighborhood of 1-5C. (For example for a 2400 mAh battery, 1 C is 2.4 A and 0.5 C is 1.2 A.) So if you're designing an application that uses these cells, it has to have enough cells to run for two hours. Otherwise you would be overtaxing the cells and suffering either inefficiency or damage.

      • Re: (Score:2, Insightful)

        by Anonymous Coward

        * Mean time to failure for a Tesla Megapack is 15 years, so "can last up to 20 years" is hardly some super boast, especially for a new product with unknown real-world performance.

        According to Elon, not exactly a rock solid source known for its spotless record of saintly honesty.

  • Zinc-Ion (not iron) (Score:5, Informative)

    by OldCoward ( 6398528 ) on Wednesday September 04, 2024 @03:11AM (#64760752)

    Zinc-Ion (not iron)

    • by CEC-P ( 10248912 )
      Dude, I read right past that but now that you mention it, I don't think two metals would make a very good battery loooool.
      • Nickel-Iron was widely used in telcos for backup. Almost indestructible. Electrolyte was a liquid lye solution, just like flooded Nickel-Cadmium batteries.
  • by Samare ( 2779329 ) on Wednesday September 04, 2024 @03:26AM (#64760764)

    Zinc as anode, manganese dioxide as cathode and an yet-undisclosed water-based electrolyte.

  • 100 MWh annually.

    That would not satisfy the capacity for even one moderate size battery deployment at one site in California. There is a site going operational at 680 MW, with 4 hours of storage.

    • by Sique ( 173459 ) on Wednesday September 04, 2024 @04:24AM (#64760844) Homepage
      But for balancing out the grid, every tiny amount helps. 100 MWh might mean that exactly those 30 min you need are covered.
    • I thought it was pretty underwhelming for a "megafactory" too. AFAICT, the project you refer to is over 2,000MWHr or more than 20 years of the output of this factory. Pictures of the factory appear to show a fairly small industrial facility. Maybe "megafactory" is just what everyone calls an end-to-end battery plant these days?

    • by Phillip2 ( 203612 ) on Wednesday September 04, 2024 @05:07AM (#64760904)

      That isn't really the point -- it's is a new battery chemistry option with different discharge characteristics from lithium. I would imagine that they will start deploying in these into existing battery facilities and use them over a long discharge period; so they will be aiming at shifting solar to overnight rather than just to the evening.

      If they work in that kind of situation, I'd expect they will be planning a GWh scale factory afterwards.

      • If you read the companies press release, it's actually a "production innovation centre". In otherwords, it is design to produce small-scale, but commercial prototypes. I don't know why they also put "megafactory" into the press release.

        • Well Elno calls factories "gigafactories" so I suppose that makes a very small factory a "megafactory".

          My garage is a kilofactory.

      • Hardly new chemistry. Zinc in various forms has been used in batteries forever all the way back to the dry cell. That is part of the appeal, it is well established technology. It does not have the energy storage capability of lithium, but in non-mobile applications that is less of an issue. Storage of hydroelectric produced power at non-peak times for example.
    • by ljw1004 ( 764174 )

      100 MWh annually.

      That would not satisfy the capacity for even one moderate size battery deployment at one site in California. There is a site going operational at 680 MW, with 4 hours of storage.

      The world installs 10GWh of grid batteries annualy. At 100MHw/year, this new factory is providing about 1% of the needs of the entire PLANET. That's hard to describe as "tiny"!

  • Good question what this might do for global zinc market. Can think of a couple companies that are very sensitive to price changes there.

    • Probably not much. We already produce orders of magnitude more zinc than lithium. So, even if this Zn ion batteries became as ubiquitous as lithium, it will still only be the minority consumer for Zn.

    • by Luckyo ( 1726890 )

      Nothing meaningful. This chemistry is going nowhere fast (hence these sort of medium sized production facilities being hailed as "megafactories"), and even if it was and we were getting CATL scale of buildup in this chemistry, we produce a hilarious amount of zinc already for sacrificial galvanic anode uses (this is what makes your car not rust like old cars used to rust, not to mention all the ships) and alloying it to make things like brass and bronze.

    • Maybe we combine this story with yesterday's and stop minting pennies in the US to free up capacity.
  • by pr100 ( 653298 ) on Wednesday September 04, 2024 @05:44AM (#64760934)

    Surely the point is that lower energy density is less important in some contexts, not that lower energy density makes them ideal?

    • I believe they meant ideal in combination with the prior list of advantages. But I agree it is poorly worded.

      • by pr100 ( 653298 )

        I realise I might be descending into pointless pedantry here (but this is /. :) ) But the low energy density isn't a positive thing even in combination with the other factors. It's *just* the other factors that make these batteries attractive for this purpose.

  • According to the International Zinc Association, a nonprofit trade association which counts Enerpoly as a member, zinc-based batteries can last up to 20 years, while lithium batteries manage about 12 years.

    Ok, all those early Tesla Model S and Nissan Leaf and other cars seem to disagree. And if thinking about applications like load shifting (like Tesla Powerwall), where the batteries are probably in a climate controlled location (unlike a car) and you probably will not do deep discharges all the way to the

    • by stooo ( 2202012 )

      In a grid storage application, having 1 cycle average use makes a 12 Year lifetime plausible for Li-Ion.

      • by shilly ( 142940 )

        Can you say what you mean by that? I don't follow it

        • by stooo ( 2202012 )

          A Li-ion Battery can have a lifetime anywhere between 1000 and 6000 cycles.
          In a grid storage application, you typically have a full cycle per 24h, while in an electric car it is much less.
          12 Years @ 1 cycle/day is about 4400 cycles.

  • Folks forget these because they truly have a lacklustre energy density, but the benefits are incredible longevity and safety and resilience. I was hoping that production of the old tech would advance a little and increase availability. Some of the ones in operation have been going 70+ years in railroad settings.

  • There is no one battery that is “the best” for all applications, rather each application has different requirements.

    For an EV, power tool, or laptop battery you want the battery to be extremely impact and vibration tolerant, have a high power density, have a high capacity density even at high discharge rates, among other qualities.

    For grid backup power the battery can be incredibly fragile and delicate as it’s installed without motion, the density of power and capacity are entirely i
  • I have solar already, but I'm not willing to have a lithium-ion battery pack installed, those things are a bit too scary and my insurance may not approve anyway. But this new tech might just be the ticket for timeshifting my solar output. On a fixed install like this size (and weight) is less of a concern, but safety and price are paramount.

  • If they don't mind a little copper mixed in, or can separate it out, now the US can recycle all its pennies [slashdot.org] ...

  • Feels clearer and more precise to show numbers like they finally did at the end (20 vs. 12 years lifetime for cells). Though I'll admit some issues might be harder to visualize that way without confusing details ('safer').

  • Not sure how changing the electrolyte alters the fire hazard that lithium ion presents. Isn't the issue there about swelling and the many tiny layers eventually touching and discharging lots of energy... which then creates lots of heat.

    Gel or water as the layer between wouldn't matter a ton, would it?

  • Zinc crustal abundance is lower than lithium [wikimedia.org]. But perhaps it is still easier to mine, though.
  • The downside is that there is something they are ideal for?

    I'm not sure that word means what you appear to think it means.

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