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Power China The Military

China's Submarines May Soon Be Powered By Lithium Batteries (interestingengineering.com) 93

The Chinese Navy could finally use lithium technology to replace the lead-acid batteries that are now used in its fleet of conventional submarines. Interesting Engineering reports: Since lithium batteries had a higher risk of catching fire or exploding, the navy was hesitant to replace the submarine fleet's current batteries with them. But, "after solving these problems, the replacement of lead-acid batteries with lithium batteries in conventional submarines is just around the corner," said Wang Feng, study lead and a submarine designer. The study claims that technical answers have been discovered through significant testing and development in China's electric car sector, and lithium batteries have been demonstrated to operate safely under difficult circumstances. The modifications could considerably improve a submarine's capacity for survival and battle, according to research that was released on October 15 in the peer-reviewed Chinese journal Marine Electric and Electronic Engineering.

For more than a decade, the Chinese military has planned to replace the lead-acid batteries in its fleet of conventional submarines with lithium technology. The lead-acid batteries on these submarines, which have not seen significant development since World War II, have proved problematic due to their poor energy storage capacity, delayed charging, limited power output, short lifespan, and harmful gas leaks, according to the paper. Nickel and cobalt, which are added to batteries to increase performance, were a contributing factor to mishaps; however, some Chinese battery manufacturers have begun using iron and phosphate in their place recently.

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China's Submarines May Soon Be Powered By Lithium Batteries

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  • Will Samsung smartphones still be banned from them?
  • by Viol8 ( 599362 ) on Wednesday November 02, 2022 @05:36AM (#63018201) Homepage

    The one where the lithium batteries in the avionics section caught fire. They did a hack fix of sealing them inside fireproof boxes but did they ever get to the bottom of why they were catching fire in the first place?

    Problem with Li batteries is they work fine for 99.999% of the time but just occasionally there's a tiny fault that leads to bad things happening. Not what you want 200m under the sea.

    • by tlhIngan ( 30335 ) <slashdot@worf.ERDOSnet minus math_god> on Wednesday November 02, 2022 @06:33AM (#63018289)

      The one where the lithium batteries in the avionics section caught fire. They did a hack fix of sealing them inside fireproof boxes but did they ever get to the bottom of why they were catching fire in the first place?

      Problem with Li batteries is they work fine for 99.999% of the time but just occasionally there's a tiny fault that leads to bad things happening. Not what you want 200m under the sea.

      Well, given it was 10 years ago when that was a problem, the 787 has been flying flawlessly since then, I'd say the problem was resolved.

      The problem turned out to be at their battery manufacturer Yuasa, which is a well-known Japanese battery maker. Apparently they had a deficient inspection system and the FAA audited the company in 2013.

      One also needs to know that the energy from the fire isn't in the materials, it's actually the stored energy of the battery itself. So if you're experimenting, discharge the battery first.

      So as long as the Chinese don't cut corners and use high quality battery makers, they should had no problems at all. Oh, who am I kidding, they're going to use cut-rate cheap batteries made at a factory running a knockoff shift of batteries.

      • by Smidge204 ( 605297 ) on Wednesday November 02, 2022 @07:02AM (#63018345) Journal

        > Oh, who am I kidding, they're going to use cut-rate cheap batteries made at a factory running a knockoff shift of batteries.

        China has a very well deserved reputation for making janky, substandard and occasionally dangerous products.

        However, they are absolutely capable of building some of the best equipment in the world, provided there is someone overseeing the operation that gives a shit. I think the Chinese government would give a shit about the quality of their military hardware, so I'd expect the quality to be world-class as well.
        =Smidge=

        • China has a very well deserved reputation for making janky, substandard and occasionally dangerous products.

          To be fair, the fault may not lie entirely with Chinese manufacturers: https://www.youtube.com/watch?... [youtube.com] (Gavin Belson at Chinese factory Silicon Valley clip)

          • by caseih ( 160668 )

            Indeed it's western demand for cheap goods that is the primary driver behind low-quality products. If the demand was for high quality, and the money offered was good, Chinese companies would step up. Of course they also learn from the best (us) on how to maximize their profits by cutting costs, so even when you do want a high-quality product manufactured you have to have sufficient oversight of the manufacturing process. Many products made in America also suffer from the same problems as the imports. Ev

            • Indeed it's western demand for cheap goods that is the primary driver behind low-quality products. If the demand was for high quality, and the money offered was good, Chinese companies would step up.

              Part of the problem is demand, or more precisely the allowance of poor quality by consumers. However, in many markets (e.g., USB cables), consumers overwhelmingly demand higher or at least functional quality even more than cheap prices, but the market continues to allow low-quality products. Why? Part of the problem is opacity in product characteristics due to lax regulation for marketing and product labeling. Other problems include poor publicity for historical product performance (e.g., doctored or ce

            • by ceoyoyo ( 59147 )

              There is demand for high quality. And cheap crap. Chinese manufacturers are happy to make both, whatever you want.

            • Right now I've got 2 items I'm going to return to Amazon because they're crap. They're both tools and I've already replaced one from a retailer who specializes in the kind of tool I bought - the other I probably should have gone to Home Depot for. The picture on Amazon didn't even match what they sent me even though it was close.

              I've been told this before, but "The most expensive tools are the ones you buy twice". I should have shopped smarter and spent a few more dollars, but at least I can still return t

        • > provided there is someone overseeing the operation
          > that gives a shit

          Yeah... kind of like the way ThinkPads went to shit after IBM sold out to Lenovo. Same laptops built by the same people in the same factory... but without IBM's QC people keeping them in line the defect rate skyrocketed and now what used to be pretty much the best PC laptop there was is now no better than any junky old dell or HP shitbox.

      • by Hodr ( 219920 )

        China produces lots of crap, but also lots of very good high quality products. Why do you assume they can't tell the difference, or that whoever is tapped to provide the batteries would lie about their capabilities or production quality? Does the Chinese government seem pretty chill about that type of stuff?

      • Re: (Score:2, Insightful)

        by AmiMoJo ( 196126 )

        Chinese EV batteries are the best in the world. Tesla uses them in some regions so it is possible to directly compare them against US made Tesla batteries in the same vehicle, and the Chinese ones offer faster charging, more peak current, and more usable capacity (less reserved).

        If you are interested then google "Tesla MIC", where MIC stands for Made In China, e.g. https://insideevs.com/news/514... [insideevs.com]

        The Chinese have also been making very big battery packs, up to megawatt hours, for many years now. They use th

    • LFP batteries don't burn the same way that NMC batteries do. The US is at a disadvantage here, since China are the only ones making LFP cells.

      • Yup, that's the important point: These aren't NMC batteries, they're LiFePO4, a much safer battery chemistry. So it's not that they're using dangerous NMC with extra safety valves fitted, they're switched to an entirely different battery technology to address the safety concerns.

        A lot of home power storage units are going to LiFePO4 for the same reason, slightly lower power density than NMC variants but much, much safer to deploy to people's homes. You can also get drop-in SLA replacements built from LiF

    • but just occasionally there's a tiny fault that leads to bad things happening.

      actually, an internal combustion engine is FAR MORE LIKELY TO CATCH FIRE https://insideevs.com/news/561... [insideevs.com]

  • I guess lithium batteries has much higher energy density per weight than acid lead, but how about per volume? Because I don't think the weight has much issue in a submarine. Sure lead is heavier than water by a magnitude, but that's offset by the air inside, isn't it?

    • Re:Energy density (Score:5, Informative)

      by drinkypoo ( 153816 ) <drink@hyperlogos.org> on Wednesday November 02, 2022 @06:25AM (#63018271) Homepage Journal

      Lithium batteries offer more power per unit of volume, too. And having the batteries be lighter also means being able to make the sub smaller.

      • ...and more maneuverable & efficient. Less inertia & energy expenditure when they speed up, slow down, & turn.
      • Lithium batteries offer more power per unit of volume, too. And having the batteries be lighter also means being able to make the sub smaller.

        Submarines are basically the whale of an oceanic fleet. Not exactly known to be svelte. Unless they're having a hell of a time finding a parking spot, I can't imagine size being that large of a factor.

        Figure out how to torpedo the human cargo if you really wanted to make them smaller, since meatsacks take up considerable space.

    • Higher density and lower weight.

      I don't have #s other than anecdotal, but I replaced a 26lb 35AH 12 volt Sealed Lead Acid (SLA) battery with a 17lb physically smaller 50AH 12 volt Lithium battery.

      That equates to about 100% more energy density (same capacity is basically 1/2 the weight if comparing equal amp hours).

      Sciency stuff:
      https://www.power-sonic.com/bl... [power-sonic.com]

  • by Randseed ( 132501 ) on Wednesday November 02, 2022 @06:00AM (#63018239)
    The first time the battery gets wet their enemies will discover that they don't even need to fire a torpedo up their ass. ;)
    • The problem with technological races is that you either adopt/adapt, or you get left behind. If you're still using WW2 in your subs when a war happens, theirs might catch fire, yours won't even get a chance to.
      Am afraid that the rest of the world will have to come up with a Li design of their own, or with something completely new, if they want to stay even.

      • Well, the American, French and British submarine fleets are all nuclear powered, so batteries are not an issue.
        • Well, the American, French and British submarine fleets are all nuclear powered, so batteries are not an issue.

          This is of course complete nonsense. Nuclear subs still have thousands of amp-hours of batteries.

        • by jwhyche ( 6192 )

          Some nuclear subs do carry batteries and diesel generators as back up sources of power. I'm not upto date on exact models and navys though.

        • Only the subs with nuclear weapons ... most others are standard diesel/electric subs.

      • Re: (Score:2, Interesting)

        by StormReaver ( 59959 )

        Am afraid that the rest of the world will have to come up with a Li design of their own, or with something completely new, if they want to stay even.

        Lithium power would be a HUGE step down for U.S. subs. Lithium Ion needs to be charged regularly. If such a sub is in a protracted chase/escape scenario with a U.S. nuclear sub, the latter will just have to wait until the former runs out of power. Then it's a sitting duck.

        • China has both nuclear and diesel-electrics

          https://www.nti.org/analysis/a... [nti.org]

          Retaining a mix of diesel subs with their nuclear ones might be OK for them since the most likely scenario is we're the ones traveling halfway around the world to fight right in their backyard.

    • I once punctured and then soaked in water a swollen, charged lipo pouch cell. Nothing, and also nothing.

      I'm not saying lithium batteries can't catch fire, I'm saying the risk is grossly exaggerated.

      Prismatic LFPs are pretty darned safe. Any kind of battery is dangerous if you abuse it. Those lead-acid batteries fill your battery room with, you know, acid if they get holed. Plus, they will offgas hydrogen if charged too fast, which is also not ideal in a submarine. They are also quite massive...

      • I once punctured and then soaked in water a swollen, charged lipo pouch cell. Nothing, and also nothing.

        I'm not saying lithium batteries can't catch fire, I'm saying the risk is grossly exaggerated.

        Thankfully manufacturers usually do more than one test.

        LiPos aren't that dangerous, but still, fire on a fucking submarine is like the worst thing imaginable so everyone should be extra careful. Spilling some acid wouldn't be anywhere near as bad in comparison.

    • by AmiMoJo ( 196126 )

      Salt water is a safe way to dispose of lithium batteries. It's one of the recommended ways to make damaged or deal batteries safe for disposal.

      https://youtu.be/Enjbp0VDQZc [youtu.be]

      As you can see in the video, nothing happens when the battery is thrown into the water. Well, nothing visible. The battery is discharging, using the salt water as a conductor conductor, with the water itself acting as a heatsink. The current is limited by the conductivity of the water, essentially acting like a big load resistor.

  • by thesjaakspoiler ( 4782965 ) on Wednesday November 02, 2022 @06:48AM (#63018317)

    You can drill a hole in the battery under load and it will not result in some nice fireworks.
    Those LTO batteries are still a bit expensive though.
    Not that it would matter for the US army where they pay private contractors $15 for a AAA battery.

  • LPF (Score:5, Interesting)

    by ballpoint ( 192660 ) on Wednesday November 02, 2022 @07:30AM (#63018393)

    We have now 8 years experience with LFP cells in an industrial environment and despite occasional misuse (shorts, overdischarge, out-of-spec low and high ambient temperatures) they have proven to be exceptionally safe with not a single incident with the cells themselves.

  • by Maury Markowitz ( 452832 ) on Wednesday November 02, 2022 @07:45AM (#63018431) Homepage

    The Japanese Soyru-class and the French Barracuda both offer Li-Ion, at least as an option. I believe the first boat in the Barracuda series does indeed use this.

    Question for the battery nerds: does li-fe-po have the same fire risks as Li-co? I don't mean in terms of the chance of it happening as a value, I'm more interested in "if they did catch fire, is the outcome as bad?".

    I ask, because here in Canada we are very much worried about fires on submarines:

    https://www.thecanadianencyclopedia.ca/en/article/chicoutimi-submarine-fire

    • LFPs have no cobalt in them so that's a definite plus, but otherwise they're still pretty goddamned bad to be around if they actually do ignite. And while it's a lot harder to make that happen, it is not impossible. The big difference in reduced flammability is that NMCs produce oxygen when they burn, and LFPs don't so you can actually smother them.

      • > and LFPs don't so you can actually smother them

        Ahhh, that does seem like a very important distinction.

        By "smother", would sea water do it? We're adding a lot of electrolytes but cutting the O2, do you know if that would help or hinder?

  • by PortHaven ( 242123 ) on Wednesday November 02, 2022 @08:20AM (#63018521) Homepage

    They have one advantage over our nuclear powered submarines. They are super-super quiet. All the coolant systems on nuclear subs make a ton of noise comparatively. This is why the Russian navy, kept a few diesel/electric subs in their fleet.

    • They are super quiet when they are motionless. All the engines are turned off, and they are just sitting there, maybe on the ocean floor. As soon as they start moving, they are as noisy as any sub.

    • by jwhyche ( 6192 )

      Do you have any idea how quiet a Los Angeles 688 is? The Russian Navy has a saying about the 688. The best way to find it is to look for a silent hole in the ocean.

  • At least I distinctly remember hearing something about Winston (LFP) being used in submarines many years ago and quality issues surrounding them.

  • I wonder what the knock-on effects might be in two areas:
    1. The weight differential is probably substantial! This would affect the buoyancy of the submarine - effectively removing ballast. In the context of an entire submarine (structure, engines, other equipment, etc.), is this a significant change?
    2. At various times and in various submarine designs, the batteries were sandwiched between the inner hull and outer hull. It was a maintenance nightmare, but made good use of otherwise dead volume, and inc
    • by habig ( 12787 )
      Ballast is easy in a sub, they've got tanks that suck water in and out for whatever net flotation is needed at the moment. Would need re-tuning of course, but ok.
  • I can imagine how horrible it will be to die of battery fumes when deep under water with no time to surface
    • I think you only need a few wires going to/from the battery; so it would be very easy to put them in a hermetically sealed compartment. Batteries would also be very easy to distribute throughout the vessel, so that would be a huge plus for balancing the sub.
  • by mi ( 197448 ) <slashdot-2017q4@virtual-estates.net> on Wednesday November 02, 2022 @10:03AM (#63018819) Homepage Journal

    Chinese military has planned to replace the lead-acid batteries in its fleet of conventional submarines with lithium technology

    They wanted to. But they could not.

    Until the US gave them the technology [npr.org]:

    The Chinese company didn't steal this technology. It was given to them — by the U.S. Department of Energy. First in 2017, as part of a sublicense, and later, in 2021, as part of a license transfer.

    100 years ago Lenin mocked "the capitalists" as fools, who'd sell him a rope, on which he'll hang them. But this was not the result of capitalist greed — this was government bureaucracy:

    Forever Energy, a Bellevue, Wash., based company, is one of several U.S. companies that have been trying to get a license from the Department of Energy to make the batteries. Joanne Skievaski, Forever Energy's chief financial officer, has been trying to get hold of a license for more than a year and called the department's decision to allow foreign manufacturing "mind boggling."

    Were we still a properly capitalist country, the developer of the technology would've held on to — and profited from — it. But we're not. The US Government owns it, and licenses it "for the greater good" — including (nay, primarily to) the licensees, whose idea of "good" is vastly different from ours.

    Does it even matter, whether this was treason or stupidity?

    • This is an article about China using Lithium batteries in their submarines. The link you posted to is an article about how the USA sold some different vanadium battery technology to them. And yet here you are with a score of +4 interesting.
      • by mi ( 197448 )

        This is an article about China using Lithium batteries in their submarines. The link you posted to is an article about how the USA sold some different vanadium battery technology to them

        Do you suppose, the situation with these Vanadium technology is unique and a once-ever leak?

        • I don't jump to wacky conclusions, no. Chinese Gubmint spent the 90's and 00's dumping billions of dollars into lithium ops while the rest of the world was saying "NIMBY".
          • by mi ( 197448 )

            There is nothing "wacky" about China getting both the actual technology and an official license to use it — before American companies did. Even if they aren't going to use it to equip their submarines, that's an outrage of its own.

            But why would they restricted themselves — and how do we know, they did? Because TFA said "Lithium" not "Vanadium"? Ha-ha...

            Chinese Gubmint spent the 90's and 00's dumping billions of dollars into lithium ops

            I don't know, if they did or not, but Americans seem to have

            • It is wacky to look at a story about Chinese lithium batteries running Chinese submarines and blame it on our sale of vanadium licenses. I am not flexible enough for these mental gymnastics, sorry.
              • by mi ( 197448 )

                a story about Chinese lithium batteries running Chinese submarines

                Are you sure, they are even that — Lithium batteries? Do you trust that:

                • Chinese military didn't deliberately misidentify the technology used?
                • Reporter(s) — for whom "Lithium" primarily means "medication" anyway — didn't accidentally mix it up"?

                Neah, of course you have no such confidence. You just sensed — correctly — that your beloved Socialism (collective ownership) is under attack and jumped to defending it on

  • Would explain a lot of things if someone told me Taiwan got to make this decision for their mainland opponents.
  • Look for the coming underwater fires.

  • Why wouldn't modern submarine design place batteries in segmented modules outside the main hull?

    • It would mean you had to pass the conductors through holes in the hull, and also make it harder to streamline. Minimizing surface area is kind of a big deal.

  • and harmful and EXPLOSIVE hydrogen gas leaks...

  • We use something called nuclear power in our submarines. We have submarines off their coast right now. I mean, like, right now. And having said that, from my place here in Southern California, I feel slightly more bad ass. Slightly, but not too far from innocence.
    • Also, I forgot to mention, if they are using batteries, then they are still powering their subs with diesel.
  • But, "after solving these problems, the replacement of lead-acid batteries with lithium batteries in conventional submarines is just around the corner," said Wang Feng, study lead and a submarine designer.

    Problems like these don't get "solved" so much as "engineered down to acceptable levels of risk". So that means instead of seeing batteries exploding in Chinese submarines at an unacceptable rate, we'll see them exploding at an acceptable rate (for whatever level of "acceptable" means for the Chinese military).

  • Nations that do not Copy/Compete/Imitate/Improve will Perish https://archive.is/tiqb8 [archive.is]

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