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Toyota's Prototype 'Cartridge' Is a Way To Make Hydrogen Portable (engadget.com) 223

Toyota and its subsidiary Woven Planet have unveiled a new portable cartridge prototype for hydrogen. "The idea is that they can be filled up at a dedicated facility, transported where needed, then returned when you receive your next shipment," reports Engadget. From the report: The cartridges would be relatively small at 16 inches long, 7 inches in diameter and about 11 pounds in weight. Toyota calls them "portable, affordable, and convenient energy that makes it possible to bring hydrogen to where people live, work, and play without the use of pipes.. [and] swappable for easy replacement and quick charging."

They could be useful for "mobility [i.e. hydrogen cars], household applications, and many future possibilities we have yet to imagine," Toyota said. It didn't mention any specific uses, but it said that "one hydrogen cartridge is assumed to generate enough electricity to operate a typical household microwave for approximately 3-4 hours."

In its press release, Toyota acknowledges that most hydrogen is made from fossil fuels and so not exactly green. But it thinks that it'll be generated with low carbon emissions in the future, and that the cartridges could help with some of the infrastructure issues. Toyota plans to test that theory by conducting proof of concept trials in various places, including its "human-centered smart city of the future," Woven City in Susono City, Zhizuoka Prefecture in Japan. The company is also "working to build a comprehensive hydrogen-based supply chain aimed at expediting and simplifying production, transport, and daily usage," it said.

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Toyota's Prototype 'Cartridge' Is a Way To Make Hydrogen Portable

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  • DOA (Score:4, Insightful)

    by Gravis Zero ( 934156 ) on Thursday June 02, 2022 @07:28PM (#62588520)

    Despite investing billions into making hydrogen fuel cells a more attractive option than batteries, Toyota has already admitted defeat. Hydrogen simply isn't a viable path forward without an absurd influx of excess suuuper cheap electrical power. However, by the time that happens, solid state lithium batteries will have already hit the market, so they'll still be a technological failure.

    • Despite investing billions into making hydrogen fuel cells

      Sure, but they aren't stupid: The money spent came from Japanese taxpayers.

  • by bunyip ( 17018 ) on Thursday June 02, 2022 @07:40PM (#62588534)

    If it can run a microwave for 3-4 hours, that's somewhere in the 1000 - 1200 watts, about 1.5 horsepower. Similar to an entry-level motor scooter. They would really need to scale this up for a car, otherwise the range will be pitiful

    • Yes, but, how many pizza slices can you nuke in 3-4 hours?

      Also what would one pizza slice look like after a 3-4 hour nuke?

    • by modecx ( 130548 ) on Thursday June 02, 2022 @08:08PM (#62588570)

      Yeah, round up and call this cartridge 5kWh. A gallon of gas (which weighs about 7 lbs) is worth somewhere around 30-35 kWh, IIRC. If you figure an ideal small engine is about 30% efficient at extracting that energy, you get about 10 kWh out of a gallon of gas, give or take.

      And you have to take cartridge cylinder back to a station, which transports it back to a fill plant and back to the station? This is pretty horrible. Why would Toyota be proud to display a prototype container that is handily beat by a lowly propane cylinder? I guess because it looks like Apple designed it? What a joke.

    • by tragedy ( 27079 )

      That works out to about 30 of these giving you about a 300 mile range in a typical electric car. About 330 lbs for the cannisters. Unknown weight for the fuel cell, but probably 200-300 lbs, then maybe a 50 mile range battery. Overall, probably slightly less weight than a typical electric car battery. I'm assuming that the cannisters would go into some sort of loader that would load up one at a time to feed to the fuel cell, maybe with a small intermediate tank to even out flow while the cannisters automat

  • by Rick Schumann ( 4662797 ) on Thursday June 02, 2022 @07:45PM (#62588538) Journal
    Bravo, Toyota.
    • by gweihir ( 88907 )

      No. Hydrogen storage is much, much harder.

      • Comment removed based on user account deletion
        • by Luckyo ( 1726890 )

          No, because hydrogen is the smallest element. Containing it within much larger elements is effectively impossible. It will always leak. Its atoms are just too small not to.

          • So extra super duper welding tank? How many "extra"s do we need here?

            • So extra super duper welding tank? How many "extra"s do we need here?

              Ten. As they say, a problem an order of magnitude different is a different problem.

          • by Khyber ( 864651 )

            "Containing it within much larger elements is effectively impossible."

            The water in the lakes, rivers, and oceans, and all those hydrocarbon chains under the ground would like to have a word with you.

            • Dihydrogen Oxide is a rather larger molecule than just H2. ;-) Same for any 'hydrocarbon chains'.
            • Yes, that's the only way realistically to make hydrogen manageable - bond the hydrogen atoms to a larger atom. Oxygen isn't a good choice, as it needs more energy to unbind than you'd get from the hydrogen. Carbon works - bond four hydrogens to a carbon, and the gas becomes much easier to contain. Bond a chain of about four carbons, you can even make it a liquid. Take it up to about eight or so, it will be a liquid anyway. And you've just reinvented compressed natural gas, LPG, and petrol. Incidentally, nit

      • Eh, LOL, now that you bring it up, I seem to recall something about hydrogen tanks developed for vehicle use, which used some sort of alloy that binds hydrogen when under pressure, but releases it when the pressure drops, or someting to that effect.
        Also, since you mention it, if what you're saying is true, then designing valves and seals for a hydrogen containment vessel of any sort would be extremely difficult, more difficult than designing the rest of the vessel, since H2 would want to squeak by just abo
        • by gweihir ( 88907 )

          I think steel does contain it, but in order to get a useful amount in a tank, you have to go to extreme pressures (10'000 psi) or cryogenic storage (at around 20K). Using some chemical binding gets around both problems, because both approaches are not really possible in a small tank. For comparison, liquid propane needs 200 psi or so and liquid Oxygen apparently needs around 400 psi.

          But I have not really looked at the details. No idea how much leakage or valves are a problem.

  • by AlanObject ( 3603453 ) on Thursday June 02, 2022 @07:53PM (#62588550)

    It isn't clear to me why this makes sense. Can anyone speak the the following?

    1. I thought one of the advantages of hydrogen is that it was fast fill compared to BEV. So is swapping out these high-pressure canisters really going to give much improvement over established hydrogen fill?

    2. So if you are going to swap out fuel carriers, why not do that with regular solid-state batteries? I realize that this didn't catch on for passenger cards for various reasons, one of which was that people didn't like the idea of trading in their batteries for potentially inferior ones on a regular basis. But a commercial truck fleet operator would have a different attitude about that.

    3. As the article states, hydrogen is already not green and is not efficent use of energy, so wouldn't this add transport costs on top of what it has to carry already? Wouldn't it be better to just manufacture hydrogen at the point of load?

    I really don't get why so much money is being put into making hydrogen happen. For my money, it ain't gonna happen.

    • I really don't get why so much money is being put into making hydrogen happen.

      1. Hydrogen sorta made some sense 30 years ago when batteries were way worse than they are today.

      2. The funding comes from the Japanese government. Politicians don't grok the Sunk Cost Fallacy.

      3. Japan has a consensus-focused society so no one wants to stick their neck out and say that the emperor has no clothes.

      For my money, it ain't gonna happen.

      Well, it isn't your money, so don't worry.

  • oh the humanity!

  • ...which is even cooler. Was blocked by the government because it was too "disruptive" but now it seems the "man" gave it the OK.

    Solid Hydrogen [youtube.com]

    • I don't believe it and there is no real evidence to convince me in that video.
  • "one hydrogen cartridge is assumed to generate enough electricity to operate a typical household microwave for approximately 3-4 hours."

    Very relatable example.

    Surprised they didn't go with 'can charge X Zunes'.

    • by emc ( 19333 )

      The typical household microwave is somewhere in the neighborhood of 1000 watts.

    • by ukoda ( 537183 )
      My thoughts exactly. I'm guessing my microwave uses around 10W in typical operation as it typically sits on the shelf doing nothing. From that I think it is fair to assume the hydrogen cartridge has a capacity of around 40Wh. I'm surprised they didn't give the weight in elephants and size in football fields. To be fair they used imperial measurements so I was still force to do mental calculations to try and relate to the size of it.
  • These sound like a great alternative for batteries, that work alongside a renewable grid
  • by ukoda ( 537183 ) on Thursday June 02, 2022 @09:57PM (#62588780) Homepage
    Ok, so it looks to be about 3 to 5kWh per cartridge and lakes up about the same space as 3 to 5kWh of Li-Ion batteries, just much lighter. So you are going to need about 8 per day to run a typical house, about the same space as a couple of Tesla Powerwalls. I can't think of a use case for them in my life.

    Like a lot of hydrogen solutions they are a solution in search of a problem.
  • by Nocturrne ( 912399 ) on Thursday June 02, 2022 @10:09PM (#62588796)

    It is has really been disappointing to watch the once strong and innovative Japanese in continuous decline for the last 30 years. Toyota and Honda had hybrid EVs in the late 90s FFS - they had a head start on Tesla of over a decade and threw it away.

    • Incumbents were too invested in fossil fuel based supply chain to act until existential threat
    • It is has really been disappointing to watch the once strong and innovative Japanese in continuous decline for the last 30 years. Toyota and Honda had hybrid EVs in the late 90s FFS - they had a head start on Tesla of over a decade and threw it away.

      As I've commented before, Toyota was an early investor in Tesla, and basically sold them the Fremont factory for cheap because they believed in Tesla so much. But then the Toyota boss had a falling out with Musk and they've been pushing this hydrogen thing ever since. Knowing a bit about how Japanese business culture works, and egos in general, it would not surprise me if this entire loss of opportunity is due to a personal hatred of Musk.

      However, I believe Panasonic is still the main battery partner for Te

  • Back of the envelope calculation: EVs gain range of 3-4 miles per hour of charge at 120v / 12-15 amps. Microwaves draw about 10 amps. So running a microwave for 3-4 hours equates to maybe 10 miles of EV range out of one of these tanks. So you'd need to carry around 40 tanks, weighing 440 pounds, to get 400 miles of range, and since it's hydrogen, you'd likely need additional heavy framing around the area where the tanks are stored.

  • by istartedi ( 132515 ) on Thursday June 02, 2022 @11:45PM (#62588902) Journal

    Put the fuel cell in the cartridge, and if you can deliver that at reasonable cost you might actually have something: a better battery.

    Of course it wouldn't recharge from the grid like a normal battery. It'd be competing with the delivery of primary cells for powering vehicles, which is pretty much a non-existent market vs. H2 which is just barely existing. IIRC, there were some proposals to use zinc pellets in cars, which would produce electricity while transforming in to zinc oxide which could then be pumped back out and re-processed. The zinc cycle isn't energetic enough though, and we're stuck with the same problem of delivering chemicals vs. delivering electricity.

    It's really hard to compete with the grid that delivers energy already and simply needs "more of the same" to power all vehicles vs. "a lot of something different".

  • "Can run a microwave for 4 hours" is a bit vague, but it should be around half a liter of gasoline, or 2-4 12v car batteries. In 18650 li-ion cells it's much better, about 300-500 of them.

  • This whole push to Hydrogen just stink of businesses investing to maintain control of a commodity that can be restricted and controlled by a few big players like the current OPEC cartel do. Rechargable batteries allow too much democratic and uncontrolled usage of energy.
    • This whole push to Hydrogen just stink of businesses investing to maintain control of a commodity that can be restricted and controlled by a few big players like the current OPEC cartel do.

      ...because electrochemical water splitting is a huge trade secret? They literally teach the process to high school students.

      Rechargable batteries allow too much democratic and uncontrolled usage of energy.

      Lithium is far from well-distributed, and the electricity to charge it is still most commonly coal, gas, oil, or even uranium...not exactly 'democratic'.

  • by joe_frisch ( 1366229 ) on Friday June 03, 2022 @02:22AM (#62589052)
    If you go to https://global.toyota/en/newsr... [global.toyota]

    its 3.3KWh / 5Kg, which is about 2X production Li Ion batteries. They don't specifiy what fuel cell efficiency they are assuming.

    This is tank only, and doesn't include the valve weight, OR the fuel cell to convert. So its not a fair comparison with batteries .

    Producing hydrogen is not very efficient, and transporting these cells will cost energy and labor.

    I don't see an obvious application that isn't better served by batteries. For a car, swapping out a dozen of these every day at a service station seems like a lot of work vs, just charging your electric car. If you really need > 300 mile range, maybe... but they we are talking about swapping at least 50X units. Its possible they are slightly better for aircraft, but when you add the weight of the (high power) fuel cell and the certification issues, it seems like a long shot.

    Hydrogen is great for high delta-V upper stage rockets, but not much else.
  • ...bottled gas? Isn't that how most Americans cook their meat? Hydrogen or propane/butane, it's all made from fossil fuels.
  • "The cartridges would be relatively small at 16 inches long, 7 inches in diameter and about 11 pounds in weight. "

    So they'll fit in dildos?
    Thank god.

  • "one hydrogen cartridge is assumed to generate enough electricity to operate a typical household microwave for approximately 3-4 hours."

    Assuming they mean a 1000w or less microwave, this means that this cart holds around 3000wh of energy.

    The dimensions of this thing are not published, but it looks MASSIVE. FAR FAR larger than the lithium ion batteries needed to store 3000wh. It may be lighter though (again who knows since it is not published).

    TL;DR what was the point of this when you can just use batteries

    • by brunes69 ( 86786 )

      I see that the other article did publish the size. However my comments still stand - it is way larger than the equivalent LiON battery. Lighter though - but not very relevant.

  • The renders make the 'cartridge' look attractive and consumer-friendly and so on in a way that your usual Air Liquide or similar vendor compressed gas tank isn't; but is there any word on whether this is just an erganomic and attractive compressed gas canister, or is it based on one of the more exotic options(adsorption on metal-organic frameworks or highly porous carbon structures; or one of the reversible chemical compounds) because of the limitations of high pressure gas storage(hydrogen; being about as
  • based on the assumption of using a future iteration, high-pressure hydrogen tank with an electricity output of approximately 3.3 kWh/unit

    Soo they hope to develop these tanks some day....
    But let's assume they do and look at the numbers. With the specs posted, the energy density works out at 325 Wh/L (same as LiFePo4) and 660 Wh/kg (3x times than LiFePo4) for a single tank. Multi-tank systems will have lower values, as you have to include the 'pack' volume and weight then....
    All of this for a system that most likely won't be possible to be charged at home overnight. I don't see the point, really.

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