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Power Earth Mars Space Science

New Solar Cells Can Convert CO2 Into Hydrocarbon Fuel (nextbigfuture.com) 195

"Researchers at the University of Illinois at Chicago have engineered a potentially game-changing solar cell that cheaply and efficiently converts atmospheric carbon dioxide directly into usable hydrocarbon fuel, using only sunlight for energy," reports Next Big Future. Slashdot reader William Robinson writes: This artificial leaf delivers syngas, or synthesis gas, a mixture of hydrogen gas and carbon monoxide. Syngas can be burned directly, or converted into diesel or other hydrocarbon fuels. The discovery opens up possibilities of clean reusable energy.
"A solar farm of such 'artificial leaves' could remove significant amounts of carbon from the atmosphere and produce energy-dense fuel efficiently..." according to the article, which adds that the process could prove useful in the high-carbon atmosphere of Mars. "Unlike conventional solar cells, which convert sunlight into electricity that must be stored in heavy batteries, the new device essentially does the work of plants, converting atmospheric carbon dioxide into fuel, solving two crucial problems at once."
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New Solar Cells Can Convert CO2 Into Hydrocarbon Fuel

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  • by joe_frisch ( 1366229 ) on Sunday July 31, 2016 @11:41AM (#52616497)

    Whether or not this is interesting really depends on the expected power / area and cost (production and operating) of an engineering version. It is better than bio-fuels by those measures?

    • by AmiMoJo ( 196126 ) on Sunday July 31, 2016 @12:32PM (#52616687) Homepage Journal

      Bio fuels require you to grow stuff, which means maintaining the soil, keeping pests away, harvesting etc. These converters should be a lot simpler.

      • bio fuel could also be alge, so it could be done in tanks, no soil needed
        • by cdrudge ( 68377 )

          You're just changing the growth medium. Soil, water...either way it has to be maintained and contain nutrients of various types.

      • by HiThere ( 15173 )

        Don't bet on it being simpler. Most artificial processes require exotic catalysts that are quickly poisoned and need to be regenerated.

        But I don't think the gadget was the point of the operation, I think they were studying the mechanism.

        • 50 years from now: "The Earth is getting too cold and plants grow suckily! We need more CO2 in the atmosphere again!"

          • Not because of this. This would be relatively carbon neutral as you use the carbon removed from the atmosphere as fuel that puts carbon back into the air.

            If this became widespread, likely the best we could hope for is enough scale to slow the release of new carbon (carbon that had been in sequestration like fossil fuels).

      • Go visit a forest some time. Lots of stuff growing without people maintaining the soil, without people keeping pests away. There is only a harvesting step.

        You need to compare on the basis of cost, not simplicity. You can have a complex process which is cheap, or a simple process which is expensive. If the cost to harvest (and refine if necessary) is less than the cost to build regular PV panels or these new type of solar cells, then the energy biol-fuels produce will be cheaper than solar (putting as
  • by Anonymous Coward on Sunday July 31, 2016 @11:45AM (#52616523)

    Because so far most of these carbon removing technologies fall way short of just planting a grove of trees. This seems like one of those problems where maybe nature is handing us a simpler solution. But for the sake of science (and keeping that funding flowing) we go out of our way to make a less efficient, more expensive machine to do the job that a tree will do for free.

    • by BenJeremy ( 181303 ) on Sunday July 31, 2016 @11:55AM (#52616561)

      To be fair, the last time I checked, my trees didn't come with a fuel hose that could fill my car's gas tank.

      Not speaking to the merits of this technology, but if it does work, it would be slick.

      • by troylanes ( 883822 ) on Sunday July 31, 2016 @12:24PM (#52616655)
        My trees do: https://en.wikipedia.org/wiki/... [wikipedia.org]
        • Trees require fertilizer and water. If these cells require less water they can be use in arid areas preserving more fertile soils for food crops.
      • by idji ( 984038 ) on Sunday July 31, 2016 @02:48PM (#52617177)
        sugarcane is pretty close to a tree with a fuel hose...
        • by DrJimbo ( 594231 )

          sugarcane is pretty close to a tree with a fuel hose...

          Excellent! I have a bunch of leftover sugar. I will be a good Samaritan and dispose of it in my neighbors' gas tanks. What a pleasant surprise it will be for each of them when they discover they have a full tank of gas.

      • Though I did see in an old magazine (Mother earth news?) where someone rigged up a stove in their car to generate CO to burn in the engine. Don't know how true the article it was, or how well the car ran...
        • by gnunick ( 701343 )

          Though I did see in an old magazine (Mother earth news?) where someone rigged up a stove in their car to generate CO to burn in the engine. Don't know how true the article it was, or how well the car ran...

          Oh yes, "wood gas" engines are a real thing.

          The process of using oxygen starved combustion to turn organic material into a combustible gas has been known for 175 years. Gustav Bischof built the first wood gasifier in 1839. By the turn of the 20th century, before the use of natural gas started proliferating in the 1930s, in many municipalities syngas produced from coal was centrally produced and distributed via pipelines to homes and businesses to use for heating and cooking. In 1901, Thomas Parker made the

        • In Western Europe this is known as the cars that ran during WW2 and under the German occupation.
          Might be something you can still find sometimes on roads of not-Pyongyang DPRK.

    • by EvilSS ( 557649 )
      On mars? Yes much better than a tree.
      • On mars? Yes much better than a tree.

        Yes!

        Where you can grow plants and get bio-diesel, plants are in competition with this device.

        Where you can't grow plants efficiently or at all - like Mars or my apartment balcony (they keep dying because I keep forgetting to water them), this may be interesting if it's better than other sunlight-to-energy systems.

      • Except, what would you do with gas on Mars? It's handy here because the other half of the reaction, oxygen, is abundant everywhere. On Mars, you'd have to also haul massive tanks of compressed oxygen around to react with your gas.

        Now, in deserts on Earth perhaps... except I suspect that this process consumes abundant water to supply the hydrogen, so it wouldn't be particularly well suited for deserts. Or Mars.

        • by DrJimbo ( 594231 )

          Except, what would you do with gas on Mars? It's handy here because the other half of the reaction, oxygen, is abundant everywhere. On Mars, you'd have to also haul massive tanks of compressed oxygen around to react with your gas.

          If only there were some way to make a solar cell to strip off the carbon from C02 in order to free up some oxygen. Seriously though, the missing ingredient here is hydrogen, not oxygen. Perhaps water in the soil could provide both oxygen and hydrogen.

    • by zmooc ( 33175 )

      It's pretty damn difficult to achieve efficiencies as low as photosynthesis in the wild so it probably does. Then again, it's pretty damn difficult to achieve efficiencies as high as photovoltaics so it is very unlikely for this technique to ever match that.

      (Note the inevitable consequence: growing crops indoors under photovoltaic powered lamps that emit frequencies that are actually usable for photosynthesis is more energy efficient and sustainable, today already. The future of agriculture is not very pret

  • by stooo ( 2202012 ) on Sunday July 31, 2016 @12:27PM (#52616663) Homepage

    I have a nice way to transform Hydrocarbon fuels into CO2

  • Because if not, I fail to see any significant advantage.

    I'm not saying this to be just contradictory to any new development in the energy industry... this is a serious question. If the amount usable energy that can be obtained by the fuel it produces in terms of energy per dollar of investment spent on the technology is not any better than what you can get from modern efficient solar cells then it makes much more sense to use solar power and electricity instead.

    • by djinn6 ( 1868030 ) on Sunday July 31, 2016 @01:22PM (#52616859)
      It does solve the storage problem though. Unlike plain solar, you don't need to buy a huge bank of batteries if you want to use it later. Much of the efficiency of solar comes from the fact that you get electricity directly, and electricity is what you use. As soon as you want the energy in a lightweight and portable form, solar loses its efficiency.

      So the main competition for this technology is not regular solar, but plants and algae, which are much cheaper to grow.
    • by davidwr ( 791652 )

      Energy density (I assume you mean energy produced in a given amount of time with a given surface area, e.g. watts/square centimeter) isn't the only factor that counts.

      How you intend to use or store the energy is also a factor.

      Pure solar typically produces either heat (sterling engine) or DC power (typical solar cell) as its direct output. Some solar devices include add-ons to convert that energy into battery storage, mechanical energy, AC power, fuel, or some other form of energy.

      This device appears to pro

  • you will NEVER be able to walk into a local Home Depot and buy one. Not tomorrow, not 5 years from now.

    I hear about solar panels as clear as glass a few years ago, that you could put on all the windows in your house to generate cheap electricity.. Still don't see them on the market, don't expect I ever will.

    For whatever reason, maybe its oil company conspiracy, maybe the ideas were fake to begin with, who knows, we see news about all kinds of new technology concepts, that NEVER COME TO FRUITION.

    • Transparent solar panels over your window would generate marginal amounts of electricity for large cost (the panels are still expensive). They'd only generate energy from light that doesn't pass, so they'd necessarily reduce the light entering your home; the darker they are, the higher their generation capacity.

      Imagine you have a choice between a 28mpg car and a 28.2mpg car. The 28mpg car costs $19,000; you can get the model with 0.2mpg more, but it costs $118,000. Which do you buy?

  • They claim to have a process to convert sunlight "directly" into synthesized fuel but in the photos and the description we see a common off the shelf photovoltaic cell in the process. Therefore this process is tied to the efficiencies of photovoltaics, and that the process can be driven by other electricity sources, such as wind, hydro, or nuclear.

    I've seen something very similar being investigated by the US Navy, the difference is that the Navy powers the process from nuclear power. They might have some

  • Here is the basic construction of the device from TFA:

    "The UIC artificial leaf consists of two silicon triple-junction photovoltaic cells of 18 square centimeters to harvest light; the tungsten diselenide and ionic liquid co-catalyst system on the cathode side; and cobalt oxide in potassium phosphate electrolyte on the anode side."

    So, the cathode is immersed in a combination of water and ethyl-methyl-imidazolium tetrafluoroborate (from TFA).

    The anode is immersed also in an electrolyte.

    The result is that "hy

  • Reading TFA, I noticed an interesting point:

    The process doesn't require light. It uses silicon photovoltaics providing power to a "reverse fuel cell" which coverts CO2 and H2O to H2 and CO (which the Fischer-Tropsch process can turn into diesel fuel, light crude, etc.)

    This means the process doesn't have to be deployed as solar panels. It could also be run in an enclosed reactor, driven by electricity. This could be used to turn power from fusion, fission, wind, space-collected-and-downlinked solar, or w

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