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The Next Notebook Battery? Lithium Polymer

Posted by Zonk on Fri Dec 08, 2006 11:36 AM
from the better-than-a-burning-notebook-in-your-lap dept.
Lewis Clarke writes "Sony is changing its course to use an old technology for its new battery manufacturing. ZDNet is reporting on comments from Sony Electronics President Stan Glasgow, where he said that Notebook makers will 'likely' soon choose to incorporate lithium polymer batteries (a battery technology that emerged nine years ago) over the current commonly used type, lithium ion batteries." From the article: "Lithium polymer batteries use lithium as an active ingredient. Lithium is a volatile material, but the lithium in these batteries isn't packed into cells as it is in lithium ion batteries. Instead, it is contained in a polymer gel. These gel batteries can't provide the same sort of energy density as lithium ion batteries, but that's now a plus."
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  • I must be getting confused - I thought Lithium Polymer was better than Lithium Ion?

    Or, giving them their full name, are they not referring to Lithium Ion Polymer batteries?
    • Re:Eh? (Score:5, Informative)

      by arth1 (260657) on Friday December 08 2006, @11:49AM (#17163514) Homepage Journal
      I must be getting confused - I thought Lithium Polymer was better than Lithium Ion?

      In some ways. It's the same thing, really, but packaged two different ways. Both are often called Li-Ion batteries, cause they are. The main two advantages of Lithium Polymer are:
      (A) They can be shaped in all kinds of odd shapes, which is a benefit when you also pack some circuitry inside the battery package, or have to use space as best you can.
      (B) They are less likely to explode, as there's resistance in the gel medium itself that hinders (if not completely prevents) a chain reaction.

      The main downside to Li-Polymer is that it is less efficient by volume and weight.

      Regards,
      --
      *Art
      • NOT TRUE (Score:5, Interesting)

        by IflyRC (956454) on Friday December 08 2006, @12:03PM (#17163702)
        Actually Lipo are more likely to explode. Most Lipo battery cells contain plastic whereas lithium ion cells are metal.

        Lipo battery warning for R/C aviation [wattflyer.com]

        I use both battery types in various aircraft. The lithium polymer is much less stable. I've seen a pack swell and be ready to vent just by knocking one off of a table onto the ground. Lithium ion will not do this. Also, keep in mind that any battery will explode if you overcharge it.
        • Actually Lipo are more likely to explode.

          If the laptop owner has a chance of survival Sony might have to replace the device. With LiPo batteries, the number of reclaims could be greatly reduced.
          • Re:NOT TRUE (Score:5, Informative)

            by IflyRC (956454) on Friday December 08 2006, @01:03PM (#17164520)
            True, its not a forceful explosion but the flames are so intense it wouldn't really matter (without the danger of shrapnel). NiMH and Nicad can explode as well but it takes a lot to get them to that point - usually overcharging. Lipos can go just from being dropped.

            How many laptops do you see being dropped? Apparently there is enough lap top dropping that IBM was advertising how sturdy their laptops were a few years back.
      • The main downside to Li-Polymer is that it is less efficient by volume and weight.

        This, I think, is not true. LiIons may be more efficient by volume, but LiPos are almost certainly more efficient per weight, because they don't have the cells, or many of the protection mechanisms that LiIon batteries have to have.

        The power/weight advantage is why they're used in applications where weight is more important than volume -- R/C aircraft, for instance. When LiPo batteries came out, they basically replaced NiCads and LiIon batteries overnight in most ultralight aircraft and helis, because they're just so much lighter (meaning that if you had an aircraft designed for NiCads, which wasn't atypical, you could get ridiculous flight time by upgrading to LiPoly cells).

        But being more efficient per volume, that I could definitely believe.

        The other big advantage I have heard is that with LiPo, you don't have to encase the batteries as heavily, so more of the weight and volume can actually be taken up with electricity-storing components, instead of as an 'exoskeleton' providing protection for the cells.
        • The other big advantage I have heard is that with LiPo, you don't have to encase the batteries as heavily, so more of the weight and volume can actually be taken up with electricity-storing components, instead of as an 'exoskeleton' providing protection for the cells.

          I'd imagine this has a lot to do with how the manufacturer decides to package the cells.

          My room mate has a few electric RC helicopters and he swapped out the NiMH cells that came with them for bare cell LiPos. They were large flat cells reminis

          • by araemo (603185) on Friday December 08 2006, @02:18PM (#17165590)
            The advantage to custom designed LiPoly batteries is that you can pack them into tons of nooks and crannies. The thing that still amazes me about your average laptop is that inside that fancy plastic battery pack is a row of cylindrical batteries with air around them. Lipoly fills in all that air with one solid mass of battery, so while the literal energy storing material may be less volume efficient, you can make more efficient use of volume in your designs as opposed to standard LiIon.
        • Re: (Score:3, Informative)

          Most laptop battery packs are comprised of lithium ion cell #18650. They are 3.6 volts (some denote them as 3.7 volts) each cell and are typically around 2200 mAH (2.2 Ampre-Hours). They are arranged in series-parallel to achieve the desired voltage (~14.4 volts) and capacity (~4400mAH).

          Lithium polymer offers a lighter package at a higher volume to achieve the same capacity and discharge current. Because of the high resistance characteristics of the polymer-only substrate, some liquid electrolyte (the
    • So now we're going to have to expect an hour and a half of battery life instead of the now standard three and a half hour. . .

      I don't know about anyone else, but I think i'd risk MORE explosive batteries if I could get like 9 hours of juice on my notebook.
      • ...if you as a consumer would indicate to the vendors that long range battery life is more important than over-all laptop or cellphone lightness. Are you willing to carry an extra pound or two in weight with your laptop? You can have (potentially) a bigger battery, that might be made better-more rugged-so that it is safer plus has good range. Consumers demand the lightest though (I call it the wimpification of society factor), so the vendors are stuck trying to accomodate that. Let the vendors know, startin
    • All of Apples MacBooks and MacBook Pros have used LiPo since their debut in January. That's why battery life was uncertain, because LiPo had not been used in notebooks before. I hear they are supposed to be better than LiIon.
  • by value_added (719364) on Friday December 08 2006, @11:40AM (#17163352)
    Why not use dilithium [wikipedia.org], instead?
  • by zappepcs (820751) on Friday December 08 2006, @11:40AM (#17163368) Journal
    Li-Poly batteries have been around awhile. Hobbyists were the first I know to use them. I don't know that they have improved in safety issues over the last few years, but perhaps you should see the following
    example of a li-poly flame out before buying li-poly batteries?

    http://www.rcgroups.com/forums/showthread.php?t=15 1687 [rcgroups.com]
    • So they don't explode, but they do catch on fire. I suppose you could put it out but that kind of choice is like the dentist asking you if you want a root cananl or a tooth extraction. Neither is very pleasant. Or so I'm told. :)
  • I thought lithium polymer was actually newer than lithium ion? Yeah, it's less energy dense, but it's a lot safer, as it is much less likely to burst into flames (though it can still happen from over charging or too-fast charging if I remember correctly).
  • Kaboom? (Score:4, Funny)

    by sam_paris (919837) on Friday December 08 2006, @11:41AM (#17163372)
    Is it just me or do others start to feel nervous when Sony start trying to push new battery technology..?
  • by creimer (824291) on Friday December 08 2006, @11:41AM (#17163386) Homepage
    Less power and less bang for the buck? Can't wait for the marketing people to spin that one.
  • Why? (Score:2, Interesting)

    Why is less energy density a plus? I would like a laptop with a long battery life, and improvements in processor technology should be used to increase battery life, not reduce the capacity of batteries.
  • "These gel batteries can't provide the same sort of energy density as lithium ion batteries, but that's now a plus."
    Why is that a plus? Seems to me having more energy stored in my battery is a good thing. Shoddy manufacturing, exploding batteries and class action lawsuits notwithstanding.
  • These gel batteries can't provide the same sort of energy density as lithium ion batteries, but that's now a plus.

    Um, no it's not a plus. Well, maybe for Sony since they can't seem to manufacture LiIon batteries reliably. But for the rest of the industry, I'm pretty sure lower engergy density (and hence shorter runtimes and/or larger batteries) is a minus. Otherwise we would all be running our laptops on alkalines.
  • lifetime? (Score:4, Interesting)

    by compro01 (777531) on Friday December 08 2006, @11:46AM (#17163470)
    unless things have changed, i remember that the original iPod used a Lithium-polymer battery and i've heard that the useful lifetime of the battery wasn't that great (less than 50% usable capasity after 1 year), which prompted Apple to switch to a regular lithium-ion for the 2nd and later generations.

    has anything changed with this or is what i've heard BS?
    • Re:lifetime? (Score:5, Informative)

      by Rob the Bold (788862) on Friday December 08 2006, @12:17PM (#17163908)
      has anything changed with this or is what i've heard BS?

      You can design in a larger and more costly charger manager in a notebook battery than you can in a digital audio player. More sophisticated charge management ICs have dead battery precharging cycles, thermimstor inputs to watch cell temp, and smarter logic for charging battery depending on state of charge when you plug it in to the charger. The smaller, low cost chargers you use for small electronics aren't nearly so smart, most just stop charging at a given voltage (or at the end of the safety timeout).

      Anyway, you can get better battery lifetime if you can afford the cost and size of a fancier charger. Doesn't mean the guys designing small devices are doing a bad job, they just have a different tradeoff to make when doing the design.

  • by syncrotic (828809) on Friday December 08 2006, @11:46AM (#17163474)
    High end notebooks from Dell, IBM, and possibly others all use lithium polymer batteries for their drivebay batteries, where space is extremely tight and the geometry is suboptimal for cylindrical cells. Li-polymer batteries can be made into very thin shapes and don't need a metal case to contain individual cells. Because of this, the energy density is actually higher. I think the reason they're not in widespread use is simply that they cost more.
    • by edmudama (155475) on Friday December 08 2006, @12:48PM (#17164310)
      exactly.

      Energy density of the raw charge storing material is lower with LiPo, but it doesn't require the same packaging/metal casing, so net energy density is higher.

      Something like 2.5 times as much power per weight as Li-Ion battery packs. It's revolutionized RC electrics.

      Models that were designed for NiMH cells and were getting 4-5 minutes of flight time, can now get 15 or more minutes of flight.
  • Bollocks. (Score:5, Insightful)

    by Control Group (105494) * on Friday December 08 2006, @11:47AM (#17163494) Homepage
    No, that's not "a plus." That's a cost-benefit tradeoff on the manufacturing side, and a risk-reward proposal on the end-user side. Lower energy density means either shorter battery life or heavier laptops. I don't think anyone would call either of those results a "plus." They're tradeoffs.

    Moreover, there are plenty of Li-ion batteries out there that haven't overheated, burned, detonated, or imploded into naked singularities causing the annihilation of life as we know it. Which means, for those batteries, you get to have longer battery life or lighter laptops sans the death and destruction result, so the move from that state to the proposed solution isn't even a tradeoff, it's a pure loss.

    Covering for the inadequacy of your manufacturing/QC processes by making a worse product that's easier to make doesn't translate into a "plus." It sounds to me that the real plus would be if they moved to a power source they've obviously got in plenty - though I think the name "spintronics" has already been taken.
    • Lower energy density means either shorter battery life or heavier laptops.

      I wouldn't be too sure about that. The article doesn't really make it clear how well the density compares.

      Energy density isn't mass density. It might mean larger notebooks or lower battery life, but it doesn't inherently mean heavier batteries.

      The article says that Lithium polimer is more flexible in form factor allowing more choices at design time, so it's not a total negative trade-off
    • I guess whether or not it's a plus depends on how much you value your life. I've used Li-Po batteries in other devices, and they're not that much worse than Li-Ion for most uses with reasonable draw. The lithium inside these batteries is dangerous, put in too much energy (typicaly more than 4.6v per cell for Li-Po) and it'll blow up regardless of whether it's a Li-Po, Li-Ion or Li-Mn. Have a look at this video clip, from a company that makes a Li-Po charging safety device, to see the effect:

      http://www.lipos [liposack.com]
  • by bill_mcgonigle (4333) * on Friday December 08 2006, @11:48AM (#17163500) Homepage Journal
    You mean "current notebook battery"?

    I'm typing this on a c2d MacBook Pro [apple.com] which lists a lithium polymer battery as its spec. Third bullet line down on that page. I also have a 5GB iPod that uses a lithium polymer battery [apple.com]. Apple went Li-Ion for later iPods, probably for higher capactiy, but I'm on my second battery in 5 years and it gives me more than 8 hours of playtime (haven't tested it beyond that).

    I guess that means Apple isn't using Sony for its current batteries?
      • I believe this well hurt sony more then anything as I am betting there are many other company's willing to make lithium ion. and the risk of one exploding is rather small really compared to how much they are used.

        Reading between the lines, I'm guessing Sony figures it cost most to handle the recalls, direct and indirect costs, than they were making as profit in the Li-Ion business. If Li-Polymer batteries are less likely to be recalled, they should profit more even if their volumes drop.
  • In the RC aircraft world, Lithium Polymer batteries are king, due to their fairly high capacity and incredibly high current draw (some packs up to 40 amps). Several folks have tried making packs out of laptop LiIon cells, but they just can't deliver the amps. Is this true that LiIon packs hold more energy but have a lower maximum amp draw? Most laptops draw about 1-3 amps I believe, so this isn't really an issue, but I am curious.
  • by Zondar (32904) on Friday December 08 2006, @11:54AM (#17163598)
    I know the model RC community does. Higher end planes and helicopters, especially the all electric ones, tend to use LiPo batteries.

    What scares me though... many many reports of fires due to overcharging (shoddy chargers). It is suggested to always charge the LiPos in a 'battery bunker', a clay pot filled with sand, with a lid.

    Isn't that what they were trying to prevent with the new laptops?
    • What scares me though... many many reports of fires due to overcharging (shoddy chargers). It is suggested to always charge the LiPos in a 'battery bunker', a clay pot filled with sand, with a lid.

      If one is really concerned about explosion/fire, I'd leave the lid off -- at least don't fasten it down. Then the setup would resemble a munitions loading bunker.

      • From one battery-bunker manufacturer's website:

        "The loose fitting lid locks on to contain the fire and allows the smoke and flame to vent around the lid and wire slot. The lid is designed to take the initial jolt that occurs."
  • Be VERY careful (Score:5, Informative)

    by IflyRC (956454) on Friday December 08 2006, @11:59AM (#17163672)
    As my name implies I fly R/C aircraft as a hobby. Within the last few years electric powered models have really taken off. Most of this is due to the Li-Po battery. Lithium Polymer batteries are a subset of Lithium Ion batteries but the design of the cells are different.

    Li-Po batteries are small and light and can produce a higher continue current than lithium ion. They are very powerful batteries.

    One of the problems though...and why I generally stay away from them is that they explode. They can easily become unstable if dropped (or crashed). I don't claim to be an expert but the cells in a lithium ion battery are metal - they can sustain an impact and vibration where as the cells in a lithium polymer are mostly plastic which can cause a mix of the chemicals inside and cause the battery to heat up until it vents and then explodes.

    Fire caused by overcharging [rcgroups.com]

    Video of a lipo battery going bad. [helihobby.com]
    • Re:Be VERY careful (Score:5, Informative)

      by bughunter (10093) <bughunter@earCOF ... t minus caffeine> on Friday December 08 2006, @06:29PM (#17168790) Journal
      My job is building hi-rel batteries for launch vehicles and spacecraft, so let me share some facts that seem to be in confusion in this forum.

      First, The distinction of Li-Poly from the general chemistry of Li-Ion is in the electrolyte. Instead of a liquid or gel electrolyte, the Li-Poly cell uses a thin sheet of conductive polymer doped with ionic compounds. Now while this polymer electrolyte has less mobility than a liquid, resulting in a lower energy density (J/cm^3) and power density (W/cm^3), in practice the manufactured shapes can be more complex than the coin or cylindrical shapes imposed by liquid electrolytes. Therefore more "battery cell" can be stuffed into otherwise unused volumes, and in many applications this maximizes the effective energy density beyond what can be achieved using cylindrical cells.

      Second, any Lithium chemistry cell using a Cobalt-alloy cathode (virtually all of them on the market today) is subject to a thermal runaway condition if the internal cell temperature exceeds 130C. This includes Li-Poly cells.

      Valence corp has patented a Lithium-Iron-Phosphate cathode chemistry that has less energy density, similar to NiCd, however the change to a Iron cathode eliminates the thermal runaway possiblity, making the cells much safer. These will soon be available commercially from DeWalt as battery packs for their cordless power tools. Here [dewalt.com] is a press release... note that Valence later bought the company referenced therein, A123 Systems. (I wonder if there's been a delay somewhere - DeWalt was marketing this much more heavily just a few months ago, now you have to do a search on their site to find any reference of it.)

      Another company, Altair Nanotechnologies, has patented a Litium Titanate Spinel anode technology that also claims to eliminate the risk of fire and improve on both the Energy Density and Power Density of vanilla Li-Ion. However they have yet to actually deliver cells (to me anyway, despite many requests). And this chemistry is not exclusive to the Iron Phosphate cathode, meaning someone with all of the proper patent licenses could combine the two and make a high energy-density, non-exploding laptop battery that does even better than the Li-Poly battery I'm using in my MacBook Pro right now.

      Finally, here's a link [batteryuniversity.com] to the "Safety Concerns" page of the "Battery University" site which is an excellent user's reference for Li-Ion secondary batteries, among others. And here is a link [valence.com] to a Valence Corp white paper that describes their LIP cells. Lastly, here is a PDF [altairnano.com] of Altair Nano's marketing material describing their claims of safety advantages their Titanium spinel material offers to commercial batteries.

  • The 17" powerbook G4 and all the macbooks and macbook pros use LiPoly batteries. So does the iPod. (Notice that the Sony recall was only for 15" and 12" powerbook g4s)
  • I use Lithium Polymer batteries in my SLR camera. It's a whacking great lump that bolts on the bottom, and although it's way better than conventional AA's (even NiMH), they are hellishy expensive ($300-£400), and they are bloody heavy! One further factor is it's a typical Sony ploy. Invent a totally unique accessory that only Sony make, and charge three times the price for it. (ie, $10 power supplies with an oddball connector they sell for £150) That's why I wont buy anything from those people.
  • Lithium (Score:3, Funny)

    by mqduck (232646) <.ten.kcudqm. .ta. .kcudqm.> on Friday December 08 2006, @12:55PM (#17164398)
    Never trust lithium. I took it for years and my brain NEVER worked. I wish I was joking.
  • by jpetts (208163) on Friday December 08 2006, @03:19PM (#17166308)
    Lithium is a metal with a melting point of 453.69 F and a boiling point of 1615F. It is a REACTIVE metal (being one of the alkali metals), but it is definitely not volatile.
    • Re:Polymer is safer (Score:4, Informative)

      by IflyRC (956454) on Friday December 08 2006, @01:05PM (#17164556)
      I'll fly my small foam electric plane with a Li-po 1500 mah 11.4 volt battery for 15 minutes. Tell me if the battery isn't hot ;) Trust me, it gets hot and you cannot re-charge these things until the battery cools down.